XPhos Pd G3

Catalog Number	ACM1445085551-1
CAS	1445085-55-1
Structure
Synonyms	Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Molecular Weight	846.46
Molecular Formula	C46H62NO3PPdS
Melting Point	146-151 °C
Purity	98%
Appearance	Powder
Application	Palladium precatalyst for facile C-N cross-coupling reactions.
MDL Number	MFCD22666043

Q&A

What are some synonyms for XPhos Pd G3?

Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

What is the molecular formula of XPhos Pd G3?

C46H62NO3PPdS

What is the melting point of XPhos Pd G3?

146-151°C (decomposition)

How should XPhos Pd G3 be stored?

Under inert gas (nitrogen or Argon) at 2-8°C

What color is XPhos Pd G3?

White to off-white

What is the reaction for which XPhos Pd G3 can be used as a palladium precatalyst?

C-N cross-coupling reactions

What are some specific uses of XPhos Pd G3 in reactions?

Cyanation reaction of heterocyclic halides, coupling of heteroaryl chlorides with polyfluoroaryl zinc reagents, coupling of 2,6-difluorophenylboronic acid with (hetero)aryl chlorides

What are some characteristics of XPhos Pd G3 as a reagent for Suzuki cross-coupling reactions?

Lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species, and accurate control of ligand: palladium ratio

What is the general description of XPhos Pd G3 as a third generation Buchwald precatalyst?

Air, moisture, and thermally-stable, highly soluble in a wide range of common organic solvents, long life in solutions, and excellent for Suzuki cross-coupling reactions