Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

Catalog Number	ACM1445085777-1
CAS	1445085-77-7
Structure
Synonyms	Dicyclohexyl-[2-[2,6-di(propan-2-yloxy)phenyl]phenyl]phosphane;methanesulfonic acid;palladium;2-phenylaniline
Molecular Weight	837.4
Molecular Formula	C43H57NO5PPdS
Canonical SMILES	CC(C)OC1=C(C(=CC=C1)OC(C)C)C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4.CS(=O)(=O)O.C1=CC=C([C-]=C1)C2=CC=CC=C2N.[Pd]
InChI	InChI=1S/C30H43O2P.C12H10N.CH4O3S.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;-1;
InChI Key	GYTUQNMMIUJBSP-UHFFFAOYSA-N
Melting Point	188-196 °C
Purity	98%
Exact Mass	836.27299
Hydrogen Bond Acceptor Count	7
Hydrogen Bond Donor Count	2
Monoisotopic Mass	836.27299
Rotatable Bond Count	9
Topological Polar Surface Area	107 Ų

Q&A

What is the molecular weight of Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)?

The molecular weight is 837.375141.

What are the product categories that Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) belongs to?

The product categories include Buchwald Ligands & Precatalysts and Buchwald Precatalysts Series.

What is the melting point of Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)?

The melting point is 188-196°C (decomposition).

How should Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) be stored?

It should be stored under inert gas (nitrogen or Argon) at 2-8 °C.

What is the color of Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)?

The color is white.

What is the InChIKey of Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)?

The InChIKey is GYTUQNMMIUJBSP-UHFFFAOYSA-N.

What is the general description of RuPhos Pd G3?

RuPhos Pd G3 is a third generation Buchwald precatalyst that can be used in cross-coupling reactions for the formation of various bonds.

What are some of the unique features of RuPhos Pd G3?

Some unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species, and accurate control of ligand: palladium ratio.

In what types of reactions can RuPhos Pd G3 be used?

It can be used in cross-coupling reactions for the formation of C-C, C-N, C-O, C-F, C-CF3, and C-S bonds.

What are some of the specific protocols in which RuPhos Pd G3 can be used as a pre-catalyst?

It can be used in protocols such as the Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles, Suzuki-Miyaura catalyst-transfer polycondensation of 3-alkylthiophenes, and Suzuki-Miyaura-cross-coupling of aminothiophenes.