Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Catalog Number	ACM12092476-2
CAS	12092-47-6
Structure
Synonyms	Bis(cycloocta-1,5-diene)dichlorodirhodium
IUPAC Name	(1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride;
Molecular Weight	493.08
Molecular Formula	C16H24Cl2Rh2
Canonical SMILES	C1CC=CCCC=C1.C1CC=CCCC=C1.[Cl-].[Cl-].[Rh].[Rh]
InChI	InChI=1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;/h2*1-2,7-8H,3-6H2;2*1H;/p-2/b2*2-1-,8-7-;
InChI Key	PDJQCHVMABBNQW-MIXQCLKLSA-L
Melting Point	243 °C
Purity	98%
Appearance	Orange yellow powder
Application	Catalyst for coupling 1,3-dienes with activate methylene compounds. Rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones. Rhodium source for asymmetric reductive aldol reaction. Cis-hydroboration of terminal alkynes. Rhodium source for [5 + 2] additions. Highly enantioselective for [2+2+2] carbocyclization reactions. Enantioselective hydroboration of cyclopropenes.
Storage	2-8°C
Complexity	72.6
Covalently-Bonded Unit Count	6
Defined Atom Stereocenter Count	0
EC Number	235-157-6
Exact Mass	491.93649
Formal Charge	-2
Heavy Atom Count	20
Hydrogen Bond Acceptor Count	2
Hydrogen Bond Donor Count	0
Isomeric SMILES	C1/C=C\CC/C=C\C1.C1/C=C\CC/C=C\C1.[Cl-].[Cl-].[Rh].[Rh]
Monoisotopic Mass	491.93649
Rotatable Bond Count	0
Topological Polar Surface Area	0 Ų

Q&A

What is the molecular formula of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The molecular formula is C16H24Cl2Rh2.

What is the molecular weight of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The molecular weight is 493.1 g/mol.

What is the IUPAC name of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The IUPAC name is (1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride.

What is the InChI of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The InChI is InChI=1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/p-2/b2*2-1-,8-7-;;;;.

What is the InChIKey of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The InChIKey is PDJQCHVMABBNQW-MIXQCLKLSA-L.

What is the canonical SMILES of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The canonical SMILES is C1CC=CCCC=C1.C1CC=CCCC=C1.[Cl-].[Cl-].[Rh].[Rh].

What is the CAS number of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The CAS number is 12092-47-6.

What is the European Community (EC) number of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The European Community (EC) number is 235-157-6.

How many covalently-bonded units are present in Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

There are 6 covalently-bonded units in Chloro(1,5-cyclooctadiene)rhodium(I) Dimer.

What are some synonyms of Chloro(1,5-cyclooctadiene)rhodium(I) dimer?

Some synonyms include Bis(1,5-cyclooctadiene)dirhodium(I) dichloride and Chloro(1,5-cyclooctadiene) rhodium (I) dimer.

When was Chloro(1,5-cyclooctadiene)rhodium(I) dimer created?

It was created on April 28, 2006.

How many hydrogen bond donor counts does Chloro(1,5-cyclooctadiene)rhodium(I) dimer have?

It has 0 hydrogen bond donor counts.

How many rotatable bond counts does Chloro(1,5-cyclooctadiene)rhodium(I) dimer have?

It has 0 rotatable bond counts.