(1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)

Catalog Number	ACM176763625
CAS	176763-62-5
Structure
Synonyms	Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride
Molecular Weight	603.74
Molecular Formula	C36H52CoN2O2
Canonical SMILES	CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O)C=NC2CCCCC2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O.[Co]
InChI	InChI=1S/C36H54N2O2.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;/h17-22,29-30,39-40H,13-16H2,1-12H3;/t29-,30-;/m1./s1
InChI Key	PCZWNUHBFITYKI-GAQUOPITSA-N
Melting Point	350+ °C
Purity	98%
Appearance	Powder
Complexity	800
Covalently-Bonded Unit Count	2
Defined Atom Stereocenter Count	2
Exact Mass	605.351722
Heavy Atom Count	41
Hydrogen Bond Acceptor Count	4
Hydrogen Bond Donor Count	2
Isomeric SMILES	CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O)C=N[C@@H]2CCCC[C@H]2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O.[Co]
Monoisotopic Mass	605.351722
Rotatable Bond Count	4
Topological Polar Surface Area	65.2 Ų

Q&A

What is the IUPAC name of (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)?

The IUPAC name of (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) is (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II).

What is the molecular weight of (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)?

The molecular weight of (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) is 603.74.

What are the product categories associated with (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)?

The product categories associated with (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) are Jacobsen Metal, Co, Kinetic Resolution Chiral Catalysts, Ligands, and Reagents, Asymmetric Synthesis, fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, and Privileged Ligands and Complexes.

What is the melting point of (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)?

The melting point of (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) is greater than 350 °C.

What is the form of (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)?

The compound is in powder form.

What is the hazardous code associated with (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)?

The hazardous code associated with (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) is Xn.

How should (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) be stored?

The compound should be kept in a dark place, in an inert atmosphere, at room temperature.

What is the color of (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)?

The compound is of orange to red to brown color.

How is (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) used in reactions?

The compound is used as a catalyst in various reactions such as the kinetic resolution of racemic, terminal epoxides, precursor to Co(III) catalyst, desymmetrization of meso-epoxides, asymmetric cyclopropanation of styrene, copolymerization of CO2 and epoxides, and enantioselective intramolecular openings of oxetanes.

What are some of the chemical properties of (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)?

The compound is described as an orange to red-brown powder.