(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate

Catalog Number	ACM210057231-1
CAS	210057-23-1
Structure
Synonyms	(1Z,5Z)-Cycloocta-1,5-diene;(2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane;rhodium;tetrafluoroborate
Molecular Weight	604.3
Molecular Formula	C26H40BF4P2Rh
Canonical SMILES	[B-](F)(F)(F)F.CC1CCC(P1C2=CC=CC=C2P3C(CCC3C)C)C.C1CC=CCCC=C1.[Rh]
InChI	InChI=1S/C18H28P2.C8H12.BF4.Rh/c1-13-9-10-14(2)19(13)17-7-5-6-8-18(17)20-15(3)11-12-16(20)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h5-8,13-16H,9-12H2,1-4H3;1-2,7-8H,3-6H2;/q;-1;/t13-,14-,15-,16-;/m0/s1
InChI Key	ZUMNNKGIZSDCBZ-MYDVBLLJSA-N
Purity	98%+
Appearance	Crystal
Exact Mass	604.16894
Hydrogen Bond Acceptor Count	5
Hydrogen Bond Donor Count	0
Isomeric SMILES	[B-](F)(F)(F)F.C[C@H]1CC[C@@H](P1C2=CC=CC=C2P3[C@H](CC[C@@H]3C)C)C.C1CC=CCCC=C1.[Rh]
Monoisotopic Mass	604.16894
Rotatable Bond Count	2
Topological Polar Surface Area	0 Ų

Q&A

What is the chemical name of (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound?

The chemical name of (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound is (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate.

What is the Molecular Weight (MW) of (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound?

The Molecular Weight (MW) of (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound is 604.25.

Under which Product Categories does (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound fall?

The compound compound falls under the Product Categories of Chiral Catalysts, Ligands, and Reagents; DuPhos/BPE; Privileged Ligands and Complexes; and organometallic complex.

What are some synonyms of (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound?

Some synonyms of (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound include (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate and Bisdimethylphospholanobenzenecyclooctadienerho.

Is (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound water-soluble?

No, (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound is insoluble in water.

What is the color of (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound?

The compound compound is red-orange in color.

Is (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound air sensitive?

Yes, (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound is sensitive to air.

What is the Safety Statement associated with (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound?

The Safety Statement for (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound is 24/25.

What are some reactions in which (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound is involved?

The compound compound is involved in the asymmetric hydrogenation of various substituted acetamidoacrylates, asymmetric reductive aminations, catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines, and more.

What are some uses of (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate compound?

The compound compound is used as a ligand for catalytic asymmetric reactions, such as asymmetric hydrogenation, asymmetric cycloaddition, and asymmetric phosphination. It is also described as a highly efficient privileged ligand.